Table 3.
1H and 13C-NMR shift assignments of WH01 and WH02 in DMSO-d6.
| WH01,(Fungichromin) | WH02 | |||
|---|---|---|---|---|
| Position | δ C | δ H | δ C | δ H |
| 1 | 170.6 | 172.6 | ||
| 2 | 58.2 | 2.48(m) | 51.9 | 2.25(ddd, J = 11.0, 8.0, 3.5 Hz) |
| 3 | 69.1 | 3.68(m) | 70.3 | 3.62(m) |
| 4 | 39.6 | 1.37(m), 1.56(m) | 39.2 | 1.37(m), 1.56(m) |
| 5 | 69.8 | 3.89(m) | 69.2 | 3.87(m) |
| 6 | 43.4 | 1.38(m) | 43.0 | 1.31(m), 1.49(m) |
| 7 | 69.6 | 3.77(m) | 69.0 | 3.68(m) |
| 8 | 43.5 | 1.31(m), 1.49(m) | 43.3 | 1.31(m), 1.49(m) |
| 9 | 68.8 | 3.87(m) | 68.7 | 3.87(m) |
| 10 | 42.4 | 1.32(m), 1.47(m) | 42.1 | 1.32(m), 1.47(m) |
| 11 | 70.1 | 3.88(m) | 70.1 | 3.88(m) |
| 12 | 38.2 | 1.37(m), 1.56(m) | 38.1 | 1.37(m), 1.56(m) |
| 13 | 67.9 | 3.14(m) | 67.9 | 3.14(m) |
| 14 | 76.1 | 3.49(d, J = 9.0 Hz ) | 76.0 | 3.49(d, J = 9.0 Hz) |
| 15 | 77.6 | 3.69(d, J =9.0 Hz) | 77.4 | 3.69(dd, J=9.0, 2.5 Hz) |
| 16 | 138.3 | 138.2 | ||
| 17 | 126.7 | 5.94(d, J = 11.0 Hz) | 126.5 | 5.94(m) |
| 18 | 127.4 | 6.45(dd, J = 15.0, 11.0 Hz) | 127.4 | 6.45(dd, J = 15.0, 11.0 Hz) |
| 19 | 130.8 | 6.26(m) | 131.0 | 6.27(m) |
| 20 | 128.6 | 6.26(m) | 128.6 | 6.26(m) |
| 21 | 132.6 | 6.35(m) | 132.2 | 6.36(m) |
| 22 | 131.8 | 6.26(m) | 131.9 | 6.28(m) |
| 23 | 132.7 | 6.35(m) | 132.4 | 6.32(m) |
| 24 | 132.8 | 6.35(m) | 132.4 | 6.32(m) |
| 25 | 134.6 | 6.02(dd, J = 15.0, 4.0 Hz) | 134.4 | 5.95(m) |
| 26 | 70.7 | 3.96(m) | 70.9 | 3.96(dd, J = 9.0, 5.0 Hz) |
| 27 | 72.7 | 4.63(m) | 72.4 | 4.63(m) |
| 28 | 17.3 | 1.19(d, J = 6.5) | 16.9 | 1.22(d, J = 6.0Hz) |
| 29 | 11.2 | 1.69(s) | 11.2 | 1.69(s) |
| 1′ | 70.6 | 3.97(m) | 28.5 | 1.44(m),1.65(m) |
| 2′ | 33.7 | 1.27(m), 1.36(m) | 25.9 | 1.14(m),1.21(m) |
| 3′ | 24.1 | 1.25(m), 1.43(m) | 27.9 | 1.23(m) |
| 4′ | 30.8 | 1.23(m) | 30.4 | 1.22(m) |
| 5′ | 21.6 | 1.25(m) | 21.3 | 1.25(m) |
| 6′ | 13.5 | 0.86(t, J = 7.5Hz) | 13.3 | 0.85(t, J = 7.5Hz) |