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Schematic view of 1 (C—gray, N—blue, O—red, S—yellow). The crucial bond lengths and angles are S-C1 = 1.75; S-N = 1.69; N1-C2 = 1.45; N1-C14 = 1.38 Å, C2-N-S = 118.3(2) °, respectively (atom numbering according to Scheme 3 and deposited cif in CCDC). All bond lengths and torsion angles are collected in Table A1 (Appendix A).
