Table 1. Development of olefin-accelerated solid-state Suzuki–Miyaura cross-coupling using mechanochemistry a .
aConditions: 1b (0.3 mmol), 2a (0.36 mmol), Pd(OAc)2 (0.009 mmol), DavePhos (0.0135 mmol), CsF (0.9 mmol), H2O (20 μL), and additive (0.12 μL mg–1) in a stainless-steel ball-milling jar (1.5 mL) with a stainless-steel ball (5 mm).