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Catalytic performance in hydrogenation of 1‐hexyne over Pd1/g‐C3N4 SAC. a) Reaction rates, selectivity to 1‐hexene. b) Representation showing isolated Pd species on carbon nitride (top) and alumina (bottom). c) stability over the course of 20 h at 343 K and 5 bar during the hydrogenation of 1‐hexyne over [Pd]mpg‐C3N4. d) Energy profile for the hydrogenation of acetylene over a single Pd atom. Reproduced with permission.61 Copyright 2015, Wiley‐VCH.
