Table 4.
List of metal SACs on 2D supports for hydrogenation of nitrobenzene
| No | Catalyst | T [°C] | S/C ratio | TOF [h−1] | S to 1 [%] | S to 4 [%] | S to 5 [%] | Refs. |
|---|---|---|---|---|---|---|---|---|
| 1 | Pt‐PMA/C | 25 | 2000 | 774 | 100 | 0 | 0 | [qv: 5c] |
| 2 | Pt(acac)2–PMA/C | 25 | 2000 | 0 | – | – | – | [qv: 5c] |
| 3 | Co–N4/C | 80 | 143 | 95.3 | 99 | 0 | 0 | [qv: 5b] |
| 4 | Co1/G | 25 | 71.4 | 1188 | – | – | 65 | 42 |
| 5 | Co–Nx/C‐600 | 110 | 409 | 36.8 | >99 | 0 | 0 | 54 |
| 6 | Co–Nx/C‐800 | 110 | 589 | 589 | >99 | 0 | 0 | 54 |
| 7 | Co–Nx/C‐900 | 110 | 818 | 579 | >99 | 0 | 0 | 54 |
| 8 | 0.2Pt/m‐Al2O3 (NP) | 25 | 2000 | 2000 | 100 | 0 | 0 | 20 |
| 9 | 0.2Pt/p‐Al2O3 (NP) | 25 | 2000 | 1450 | 62 | 2.7 | 34.2 | 20 |
| 10 | Pt/AC (NP) | 25 | 2000 | 917 | 50.9 | 2.7 | 1.8 | [qv: 5c] |