Table 5.
No | Catalyst | S/C ratio | T [°C] | ATOF a) [h−1] | S to phenol [%] | Refs. |
---|---|---|---|---|---|---|
1 | GN | – | 25 | – | 97.1 | 13 |
2 | FeN4/GN‐1.5 | 335 | 25 | 2.1 | 89.4 | 13 |
3 | FeN4/GN‐2.7 | 186 | 25 | 84.7 | 94.3 | 13 |
4 | FeN4/GN‐2.7 | 186 | 25 | 1.8 | 80.0 | 13 |
5 | FeN4/GN‐4.0 | 126 | 25 | 1.2 | 79.8 | 13 |
6 | FeN4/GN‐1.5 | 335 | 0 | 1.1 | 87.6 | 13 |
7 | FeN4/GN‐2.7 | 186 | 0 | 0.71 | 89.8 | 13 |
8 | SA‐Fe/CN | 697 | 60 | 13.1 | 94 | 48 |
9 | Co‐ISA/CNS | 884 | 25 | 150 | 93.3 | 96 |
10 | Co‐ISA/CNS | 884 | 25 | 6.3 | 89.7 | 96 |
ATOF means the number of converted reactants per metal atom per hour on average.