Table 1.
Derivatized pharmaceutical and personal care GC-MS products obtained by injecting target standards.
Target Analytes TMS Derivative | Type | Chemical Formula Trimethylsilyl (TMS) | Retention Time Minutes | Fragment Pattern TMS Derivative (m/z) | Selected Ion Monitored (m/z) | Similarity Index |
---|---|---|---|---|---|---|
Methamphetamine | Illicit drug | C10H15N | 5.450 | 58, 91, 134, 148 | 58, 91 | 84 |
Salicylic acid | NSAID | C7H6O3 | 6.345 | 73, 135, 193, 209, 267 | 135, 267 | 82 |
Acetylsalicylic acid | NSAID | C9H8O4 | 6.467 | 65, 73, 120, 195, 210, 268 | 120, 195 | 95 |
Nalidixic acid | Antibiotic | C12H12N2O3 | 6.914 | 73, 116, 162, 180, 236, 301 | 180, 236 | 89 |
Ibuprofen | NSAID | C13H18O2 | 7.105 | 73, 117, 160, 191, 263, 278 | 117, 160 | 80 |
Propylparaben | Antifungal agent | C10H12O3 | 7.458 | 73, 116, 162, 180, 236, 301, 251 | 162, 236 | 80 |
Phenacetin | Analgesic | C10H13NO2 | 7.800 | 53, 109, 137, 179, 209 | 109, 179 | 96 |
Acetaminophen | NSAID | C8H9NO2 | 8.000 | 73, 106, 166, 181, 223 | 181, 223 | 88 |
Phenoxyphenol | Standard | C12H10O2 | 8.250 | 73, 122, 150, 185, 258 | 150, 258 | 91 |
Morphine | Opioid analgesic | C17H19NO3 | 8.450 | 75, 103, 119, 174, 204, 232, 285 | 232, 204 | 81 |
Caffeine | Stimulant | C8H10N4O2 | 8.912 | 109, 194 | 109, 194 | 81 |
Naproxen | NSAID | C14H14O3 | 10.685 | 173, 41, 185, 243, 302 | 185, 243 | 88 |
procaine | Anaesthetic | C13H20N2O2 | 10.950 | 58, 86, 164 | 58, 86 | 81 |
Triclosan | Disinfectant | C12H7Cl3O2 | 11.250 | 109, 185, 200 | 109, 200 | 95 |
Meclofenamic acid | NSAID | C14H11Cl2NO2 | 11.990 | 73, 152, 208, 223, 313, 180 | 223, 313 | 95 |
Ketoprofen | NSAID | C16H14O3 | 12.105 | 73, 105, 165, 179, 253, 282, 311 | 282, 311 | 88 |
Diclofenac | NSAID | C14H11Cl2NO2 | 12.806 | 73, 93, 151, 214, 277, 367 | 214, 367 | 91 |
Carbamazepine | Anticonvulsant | C15H12N2O | 13.654 | 63, 96, 165, 193, 236 | 193, 236 | 88 |
Chloramphenicol | Antibiotic | C11H12Cl2N2O5 | 13.921 | 73, 93, 147, 208, 225, 361, 451 | 208, 225 | 82 |
Cocaine | Illicit drug | C17H21NO4 | 14.530 | 77, 82, 152, 182, 272, 303 | 82, 182 | 91 |
Procainamide | Transformation | C11H26NO2 | 15.450 | 85, 99, 192 | 86, 99 | 88 |
2-phenylindolizine | Metabolite | C14H11N | 15.960 | 63, 96, 165, 193 | 165, 193 | 80 |
Sulfamethoxazole | Antibiotic | C10H11N3O3S | 16.500 | 65, 92, 156, 189, 253 | 92, 156 | 91 |
Chlorpromazine | Antipsychotic | C17H19ClN2S | 17.605 | 58, 214, 232, 272, 315 | 58, 214 | 94 |
Lactose | Metabolite | C36H86O16 | 18.560 | 73, 103, 147, 204, 243, 319, 521 | 204, 243 | 81 |
Sulfamethazine | Antibiotic | C12H14N4O2S | 20.052 | 92, 108, 156, 213, 277 | 92, 213 | 95 |
Clozapine | Antipsychotic | C18H19ClN4 | 21.750 | 70, 99, 164, 192, 243, 268, 326 | 192, 243 | 93 |