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. 2019 Aug 13;10(38):8840–8849. doi: 10.1039/c9sc02149c

Fig. 3. Molecular structure of (a) [(LN)2U(O)]3, 6, and (b) [(LN)2U(μ-O)U(μ-κ2-O,N-OC( Created by potrace 1.16, written by Peter Selinger 2001-2019 C)SiMe2NSiMe3)U(LN)2], 7, with thermal ellipsoids drawn at the 50% probability level. Hydrogen atoms have been omitted for clarity. The asymmetric unit contains 2 independent molecules. Only 1 is shown for sake of clarity. Selected bond lengths and angles of [(LN)2U(O)]3: U–(Namide)avg, 2.28(1) Å; U–(Ooxo)avg, 2.10(2) Å; U–O–U, 144(1)°. Selected bond lengths and angles of [(LN)2U(μ-O)U(μ-κ2-O,N-OC( Created by potrace 1.16, written by Peter Selinger 2001-2019 C)SiMe2NSiMe3)U(LN)2]: U1–(Namide)avg, 2.27(4) Å; U2–(Namide)avg, 2.26(1) Å; U1–O1, 2.082(15) Å; U2–O1, 2.130(15) Å; U1–N3, 2.256(16) Å; U2–O2, 2.074(13) Å; C36–C37, 1.32(3); U1–O1–U2, 150.3(7).

Fig. 3