Fig. 5. Molecular structure of [NBu4][{(LO)3U}2(μ-NH)(μ-H)], 9, with thermal ellipsoids drawn at the 50% probability level. Hydrogen atoms of the siloxide ligands, and a toluene molecule have been omitted for clarity. Selected structural parameters: U–(Osiloxide)avg = 2.17(1) Å, U–Navg = 2.216(2) Å, U–Havg = 2.27(3) Å, U1–N1–U2 = 116.71(14)°, U1–H1–U2 = 113 (2)°.
