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. 2019 Oct 28;4(20):18663–18667. doi: 10.1021/acsomega.9b02587

Table 3. 31P NMR Data for Paraoxon–C70-OH Fullerene Interactionsa.

[C70-OH] (M) C70:paraoxon ratio δ (ppm) Δδ (ppm) 1/[C70] (M)−1 1/Δδ (ppm–1)
6.3 × 10–2 70:1 9.10 3.03 15.769 0.330
4.5 × 10–2 50:1 8.96 2.89 22.076 0.346
3.6 × 10–2 40:1 8.82 2.75 27.595 0.364
2.7 × 10–2 30:1 8.6 2.53 36.793 0.395
1.8 × 10–2 20:1 7.69 1.62 55.190 0.617
9.1 × 10–3 10:1 6.97 0.90 110.380 1.111
4.5 × 10–3 5:1 6.58 0.51 220.760 1.961
0.00 0 6.07 N/A N/A N/A
a

Δδ (ppm) represents the observed chemical shift (δ) change for that specific fullerene-containing sample vs the δ observed for the paraoxon control.