Skip to main content
. 2019 Oct 29;52(21):8339–8345. doi: 10.1021/acs.macromol.9b01852

Table 1. Polymerization Condition at Each Run and the Corresponding Results.

entry [initiator]a [monomer]b solvent temp (°C) Dn (μm) CV (%) Dz (μm) yield (%)
1 1% 2% phenyl acetate 95 0.62 7.5 0.79 12
2 2% 2% phenyl acetate 95 1.05 6.5 1.13 75
3 3% 2% phenyl acetate 95 0.92 5.0 1.06 71
4 4% 2% phenyl acetate 95 0.97 3.7 1.08 73
5 2% 1% phenyl acetate 95 0.82 5.4 0.84 31
6 2% 3% phenyl acetate 95 0.95 6.7 1.02 67
7 2% 4% phenyl acetate 95 1.03 6.8 1.07 70
8 2% 2% phenyl acetate 65 0.70 5.2 0.88 89
9 2% 2% ethyl acetate 65 1.44 5.4 1.79 57
a

w/w ratio to monomer.

b

w/v ratio to solvent; Dn = number-average diameter determined via SEM (min. 100 particles); Cv = Dn/SD; Dz = z-average diameter determined via DLS; yield = weight of particles/weight of monomers.