Table 3. Summary of Data for the Complex [V(NAr)Cl2(OAr)] (6a) or [V(NAd)Cl2(L)] [B, L = 2-(2′-Benzimidazolyl)-6-methylpyridine] in the Presence of Me2AlCl or MAOa.
| complex 6a | 6a + MAO (10 equiv) | 6a + Me2AlCl (50 equiv) | complex Bb | B + Me2AlCl (10 equiv)b | ||||||
|---|---|---|---|---|---|---|---|---|---|---|
| atom | C.N. | r (Å) | C.N. | r (Å) | C.N. | r (Å) | C.N. | r (Å) | C.N. | r (Å) |
| N(O) | 2.4 ± 0.3 | 1.80 ± 0.05 | 1.8 ± 0.2 | 1.73 ± 0.04 | 1.3 ± 0.2 | 1.64 ± 0.04 | 1.7(2) | 1.683(5) | 0.9(3) | 1.64(2) |
| N | 1.2(8) | 2.290(42) | ||||||||
| Cl | 1.9 ± 0.2 | 2.1 8± 0.03 | 1.4 ± 0.2 | 2.17 ± 0.03 | 2.0 ± 0.2 | 2.45 ± 0.03 | 1.6(2) | 2.293(3) | 2.6(1) | 2.455(7) |
a
Atom: neighbor atom, C.N.: coordination number, r: bond length.
b
Data cited from ref (42).