Table 1. Bulk polymerization of methyl methacrylate initiated using visible light in presence of TTT–DTDA and TTT–BTDA COFs and triethylamine as co-initiators, at room temperature a .
| COF | Conversion (%) | Molecular wt (Mn) (g mol–1) | Dispersity b Mw/Mn |
| TTT–DTDA | 63% | 2.3950 × 105 | 2.2161 |
| TTT–BTDA | 54% | 2.4292 × 105 | 2.9246 |
| No catalyst c | 5% | 0.9437 × 102 | 1.1328 |
a λ = 420–700 nm, time = 12 h, [MMA] = 9.39 mmol, [TEA] = 0.35 mmol, 20 mg of as-synthesized COF initiator.
bNumber-average molecular weight (Mn) and molecular weight distribution (Mw/Mn) determined by GPC.
cWithout any addition of COF initiator.