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. 2019 Sep 13;58(43):15496–15503. doi: 10.1002/anie.201908978

Scheme 2.

Scheme 2

(a) Transition metal behavior of main group metals exemplary shown for H−H bond activation (from left to right: transition metal, mononuclear AlI species or RSnSnR). (b,c) Examples for C−H bond activation at AlI centers. (d) Activation and dearomatization of benzene by a cationic Ca complex and (DIPPBDI)Al. (e) Pd catalyzed benzene alumination. (f) Oxidative addition of an aluminyl anion to the C−H bond in benzene.