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Fig. 2. Structural modification tree of pyrethroids. Most synthetic pyrethroids contain asymmetric carbons in their structures, and their insecticidal actions are very stereospecific. Commercialized products are either isomer mixtures, a single isomer, or various product specifications. In many cases, they have been replaced by a resolved form (chiral switch). Only the most important isomers are shown here. Generally, both cis- and trans-isomers on the cyclopropane ring are insecticidal, but cis-isomers are preferred in agricultural use and trans-isomers are preferred in household use; however, there are some exceptions.