Table 7.
Polymerizable DESs.
| Composition, Molar Ratio | Initiator | Conversion (%) | Ref. |
|---|---|---|---|
| Acrylic acid/Choline chloride, 5:8 | 1,1-bis(tert-butylperoxy)-3,3,5-trimethylcyclohexane (Luperox 231) (0.2 mol %) | 100 | [75] |
| Acrylic acid/Choline chloride, 5:8 | Luperox 231 (0.3 mol %) | 100 | [75] |
| Acrylic acid/Choline chloride, 5:8 | Luperox 231 (0.4 mol %) | 94 | [75] |
| Acrylic acid/Choline chloride, 5:8 | Luperox 231 (0.5 mol %) | 93.6 | [75] |
| Acrylic acid/Choline chloride, 5:8 | Luperox 231 (0.7 mol %) | 94.2 | [75] |
| Acrylic acid/Choline chloride, 5:8 | Luperox 231 (1 mol %) | 92.5 | [75] |
| Methacrylic acid/Choline chloride, 1:2 | Luperox 231 (0.2 mol %) | 98 | [75] |
| Methacrylic acid/Choline chloride, 1:2 | Luperox 231 (1 mol %) | 100 | [75] |
| Acrylic acid/Lidocaine hydrochloride, 3:1 | Luperox 231 (1.5 mol %) | 100 | [75] |
| Acrylic acid/Lidocaine hydrochloride, 3:1 | Luperox 231 (0.2 mol %) | 100 | [75] |
| Acrylamide/Choline chloride, 1:2 | Luperox 231 (0.1 mol %) | 90 | [75] |
| Acrylic acid/Choline chloride + acrylamide, 1:2 | Luperox 231 (0.03 mol %) | 100 | [75] |
| Acrylic acid/Choline chloride + N-isopropylacrylamide, 1:2 | Luperox 231 (0.03 mol %) | 100 | [75] |
| Choline chloride/Acrylic acid, 5:8; 1:2 | Crosslinkers: poly(ethylene glycol) diacrylate and 2-hydroxy-4-(2-hydroxyethoxy)-2-methylpropiophenone photoinitiator | [76] | |
| Choline chloride/Itaconic acid, 1:1 | Initiator: N,N′-methylenedisacrylamide, ammonium sulphate | >90 | [65] |
| Choline chloride/Itaconic acid, 1:1 | Initiator: N,N′-methylenedisacrylamide (2–15 mol %, ammonium sulphate | 29–100 | [64] |
| Choline chloride/Itaconic acid, 1:1 | Initiator: N,N′-methylenedisacrylamide, ammonium sulphate, second inert diluent–poly(ethyleneglycol) | 64–74 | [64] |
| Choline chloride/Itaconic acid, 1:1 | Initiator: N,N′-methylenedisacrylamide (2-15 mol %, ammonium sulphate | 90–99 (post-gel stage) | [72] |
| Choline chloride/Itaconic acid, 1:1 | Initiator: N,N′-methylenedisacrylamide (2-15 mol %, ammonium sulphate | 90–99 (pre-gelation stage) | [72] |
| Choline chloride/Itaconic acid/Water, 1:1:1 | Initiator: ammonium sulphate | 96 | [71] |
| Tetraethylammonium chloride/Itaconic acid/Water, 1:1:1 | Initiator: ammonium sulphate | 87 | [71] |
| Lidocaine hydrochloride/Acrylic acid, 1:3 | Luperox 231, as thermal initiator and ethylene glycol methacrylate or pentaerithrytol triacrylate | 100 | [66] |
| Lidocaine hydrochloride/Methacrylic acid, 1:3 | Luperox 231, as thermal initiator and ethylene glycol dimethacrylate or pentaerithrytol triacrylate | 100 | [66] |
| Lidocaine hydrochloride/Acrylic acid + Lidocaine hydrochloride/Methacrylic acid (1:1), mixture | Luperox 231, as thermal initiator and ethylene glycol dimethacrylate or pentaerithrytol triacrylate | 100 | [66] |
| 2-Cholinium bromide methacrylate/Citric acid, 1:1 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | [73] | |
| 2-Cholinium bromide methacrylate /Amidoxime methacrylate, 1:1 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | [73] | |
| Ammonium tetraol/citric acid, 3:4 | Polycondensation | ≈90 | [73] |
| Ammoniumtriol/citric acid, 1:1 | Polycondensation | ≈90 | [73] |
| Ammonium tetraol/citric acid/terephthalic acid, 6:5:4 | Polycondensation | ≈90 | [73] |
| Ammonium triol/citric acid/terephthalic acid, 8:5:4 | Polycondensation | ≈90 | [73] |
| Cholinium bromide methacrylate/Citric acid, 1:1 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |
| Cholinium bromide methacrylate/Citric acid, 2:3 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |
| Cholinium bromide methacrylate/Oxalic acid, 1:2 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |
| Cholinium bromide methacrylate/Malonic acid, 1:2 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |
| Cholinium bromide methacrylate/Maleic acid, 1:2 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |
| Cholinium bromide methacrylate/Benzeneimidamide, 1:1 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |
| Cholinium bromide methacrylate/Trifluorobenzeimidamide, 1:1 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |
| Cholinium bromide methacrylate/Propanimidamide, 1:1 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |
| Cholinium bromide methacrylate/Diaminopyridine, 1:1 | Photopolymerization, crosslinker ethylene glycol dimethacrylate, photoinitiator 2-hydroxy-2-methylpropiophenone | 100 | [74] |