Table 2.
Major and trace elements of the studied rocks.
| Sample No | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 | 12 | 13 | 14 | 15 | 16 | 17 | 18 | 19 | 20 |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Major oxides (wt. %) | ||||||||||||||||||||
| SiO2 | 20.15 | 25.78 | 49.27 | 52.03 | 40.05 | 16.40 | 10.35 | 3.15 | 9.35 | 5.23 | 10.05 | 14.11 | 15.12 | 16.35 | 5.95 | 9.05 | 7.85 | 2.35 | 1.18 | 0.59 |
| TiO2 | 0.15 | 0.18 | 1.88 | 0.10 | 0.17 | 0.27 | 0.06 | 0.07 | 0.12 | 0.07 | 0.11 | 0.03 | 0.04 | 0.80 | 0.04 | 0.10 | 0.10 | 0.02 | 0.03 | 0.02 |
| Al2O3 | 1.82 | 1.86 | 1.09 | 1.11 | 2.59 | 3.26 | 0.59 | 0.83 | 1.07 | 1.09 | 1.85 | 0.47 | 0.55 | 0.91 | 0.40 | 1.23 | 0.94 | 0.37 | 0.22 | 0.11 |
| Fe2O3 | 6.16 | 22.15 | 35.26 | 11.63 | 7.31 | 4.15 | 3.30 | 1.61 | 1.02 | 1.11 | 4.75 | 1.15 | 1.15 | 31.04 | 0.70 | 3.90 | 3.02 | 25.05 | 0.33 | 0.17 |
| MnO | 33.40 | 25.14 | 4.77 | 27.05 | 17.77 | 53.02 | 54.95 | 47.05 | 35.70 | 41.07 | 51.03 | 39.05 | 41.27 | 31.02 | 24.35 | 31.15 | 61.02 | 35.12 | 5.74 | 3.28 |
| MgO | 0.15 | 0.12 | 0.02 | 0.02 | 1.40 | 0.73 | 0.87 | 0.40 | 0.67 | 0.45 | 0.12 | 0.24 | 0.02 | 0.20 | 0.37 | 0.43 | 0.32 | 0.20 | 0.39 | 0.34 |
| CaO | 19.43 | 7.76 | 0.55 | 0.57 | 13.67 | 4.15 | 10.45 | 25.23 | 27.30 | 27.15 | 16.03 | 18.25 | 19.05 | 17.23 | 38.16 | 29.15 | 8.65 | 13.05 | 51.35 | 53.26 |
| Na2O | 0.80 | 2.05 | 0.02 | 0.01 | 1.05 | 1.15 | 0.85 | 0.57 | 1.06 | 0.95 | 0.55 | 1.25 | 0.51 | 0.46 | 0.80 | 0.58 | 0.80 | 0.55 | 0.18 | 0.05 |
| K2O | 0.91 | 0.46 | 0.25 | 0.67 | 0.62 | 2.09 | 3.21 | 1.11 | 1.02 | 1.05 | 0.95 | 0.96 | 0.51 | 0.50 | 0.60 | 0.30 | 0.82 | 0.08 | 0.10 | 0.02 |
| P2O5 | 0.08 | 0.04 | 0.02 | 0.00 | 0.02 | 0.11 | 0.07 | 0.05 | 0.05 | 0.05 | 0.08 | 0.01 | 0.01 | 0.02 | 0.03 | 0.05 | 0.04 | 0.10 | 0.02 | 0.02 |
| L.O.I | 15.57 | 13.55 | 6.06 | 6.05 | 14.57 | 12.90 | 14.13 | 19.03 | 21.62 | 20.75 | 13.12 | 23.55 | 21.03 | 19.23 | 26.51 | 22.28 | 13.45 | 15.83 | 39.95 | 41.68 |
| Elements (wt. %) | ||||||||||||||||||||
| Si % | 9.42 | 12.05 | 23.03 | 24.32 | 18.72 | 7.67 | 4.84 | 1.47 | 4.37 | 2.44 | 4.70 | 6.60 | 7.07 | 7.64 | 2.78 | 4.23 | 3.67 | 1.10 | 0.55 | 0.28 |
| Al % | 0.96 | 0.98 | 0.58 | 0.59 | 1.37 | 1.73 | 0.31 | 0.44 | 0.57 | 0.58 | 0.98 | 0.25 | 0.29 | 0.48 | 0.21 | 0.65 | 0.50 | 0.20 | 0.12 | 0.06 |
| Fe % | 4.31 | 15.49 | 24.66 | 8.13 | 5.11 | 2.90 | 2.31 | 1.13 | 0.71 | 0.78 | 3.32 | 0.80 | 0.80 | 21.71 | 0.49 | 2.73 | 2.11 | 17.52 | 0.23 | 0.12 |
| Mn% | 25.87 | 19.47 | 3.69 | 20.95 | 13.76 | 41.06 | 42.56 | 36.44 | 27.65 | 31.81 | 39.52 | 30.24 | 31.96 | 24.02 | 18.86 | 24.12 | 47.26 | 27.20 | 4.45 | 2.54 |
| Mg % | 0.09 | 0.07 | 0.01 | 0.01 | 0.84 | 0.44 | 0.52 | 0.24 | 0.40 | 0.27 | 0.07 | 0.14 | 0.01 | 0.12 | 0.22 | 0.26 | 0.19 | 0.12 | 0.24 | 0.21 |
| Na % | 0.59 | 1.52 | 0.01 | 0.01 | 0.78 | 0.85 | 0.63 | 0.42 | 0.79 | 0.70 | 0.41 | 0.93 | 0.38 | 0.34 | 0.59 | 0.43 | 0.59 | 0.41 | 0.13 | 0.04 |
| Trace elements (ppm) | ||||||||||||||||||||
| V | 1084.00 | 570.20 | 721.10 | 179.30 | 277.80 | 1311.20 | 634.60 | 330.40 | 410.20 | 368.10 | 368.10 | 559.10 | 536.40 | 353.60 | 355.00 | 415.00 | 175.00 | 1450.00 | 142.00 | 59.00 |
| Cr | 163.40 | 82.60 | 82.20 | 123.90 | 153.40 | 195.00 | 260.40 | 56.40 | 159.60 | 139.90 | 139.90 | 93.30 | 161.40 | 3742.00 | 67.30 | 121.40 | 19.80 | 93.40 | 58.80 | 56.90 |
| Co | 22.90 | 9.50 | 22.30 | 25.30 | 41.20 | 27.30 | 26.10 | 113.30 | 48.50 | 55.30 | 55.30 | 31.50 | 32.50 | 64.20 | 42.10 | 32.50 | 38.60 | 41.50 | 10.80 | 5.30 |
| Ni | 25.50 | 11.00 | 10.00 | 10.00 | 10.00 | 11.00 | 10.00 | 11.00 | 1200.00 | 14.00 | 14.00 | 11.00 | 11.00 | 12.00 | 0.90 | 0.85 | 0.90 | 0.85 | 0.90 | 0.80 |
| Cu | 15.10 | 4.50 | 3.50 | 18.00 | 47.90 | 4.20 | 6.70 | 26.20 | 8.50 | 15.50 | 15.50 | 51.00 | 24.90 | 15.10 | 0.90 | 19.70 | 23.90 | 51.00 | 0.90 | 0.90 |
| Zn | 1086.00 | 9920.00 | 1000.00 | 1457.00 | 1802.00 | 1357.00 | 1272.00 | 573.30 | 385.00 | 332.00 | 332.00 | 433.00 | 446.00 | 473.00 | 869.10 | 1151.70 | 2001.50 | 1854.40 | 704.60 | 350.20 |
| Rb | 1.00 | 0.20 | 1.20 | 2.70 | 2.60 | 3.80 | 10.80 | 2.10 | 2.80 | 1.10 | 1.10 | 24.00 | 2.70 | 6.70 | 2.20 | 3.70 | 2.30 | 1.30 | 2.10 | 2.60 |
| Sr | 3917.00 | 2329.00 | 2525.00 | 1609.00 | 1991.00 | 2534.00 | 1864.00 | 48.91 | 3349.00 | 3349.00 | 3349.00 | 2656.00 | 1563.00 | 2094.00 | 1152.00 | 875.00 | 1015.00 | 1450.00 | 445.00 | 265.00 |
| Zr | 246.00 | 163.00 | 178.00 | 106.00 | 138.00 | 178.00 | 191.00 | 347.00 | 244.00 | 250.00 | 250.00 | 189.00 | 108.00 | 163.00 | 245.00 | 125.00 | 212.00 | 45.00 | 85.00 | 55.30 |
| Nb | 1> | 1> | 1> | 1.60 | 1.00 | 1> | 8.00 | 1> | 1> | 1> | 1> | 1> | 1.00 | 0.90 | 1> | 1.50 | 1> | 3.30 | 2.20 | 2.30 |
| Mo | 28.40 | 4.70 | 6.10 | 4.30 | 3.70 | 7.20 | 4.30 | 9.70 | 9.60 | 7.10 | 7.10 | 9.10 | 9.00 | 9.40 | 8.80 | 9.60 | 7.10 | 5.40 | 4.30 | 9.00 |
| Ba | 5900.00 | 5700.00 | 4500.00 | 18000.00 | 4700.00 | 11000.00 | 6200.00 | 13000.00 | 3300.00 | 4800.00 | 4800.00 | 4300.00 | 5800.00 | 4800.00 | 9100.00 | 8500.00 | 17500.00 | 5500.00 | 445.00 | 665.00 |
| La | 1> | 317.80 | 108.90 | 84.20 | 342.20 | 1> | 1> | 206.10 | 2.00 | 1> | 1> | 1> | 91.80 | 93.10 | 1> | 1> | 1> | 107.20 | 186.10 | 76.80 |
| Yb | 3.70 | 1.30 | 1.10 | 0.50 | 0.60 | 1.20 | 1.20 | 1.40 | 1.50 | 2.10 | 2.10 | 1.60 | 1.00 | 1.20 | 2.20 | 1.40 | 1> | 2.30 | 1.80 | 1.60 |
| Hf | 16.00 | 9.70 | 10.40 | 6.10 | 7.80 | 10.20 | 12.10 | 26.00 | 17.60 | 14.70 | 14.70 | 13.40 | 6.30 | 9.30 | 7.60 | 3.90 | 7.40 | 1.00 | 2.80 | 2.70 |
| Ta | 2.80 | 0.40 | 2.30 | 2.00 | 1.60 | 2.60 | 2.10 | 2.90 | 1.40 | 1.60 | 1.60 | 1.50 | 2.00 | 2.10 | 1.50 | 2.60 | 1.60 | 2.70 | 2.90 | 2.00 |
| As | 850.00 | 870.00 | 810.00 | 770.00 | 790.00 | 810.00 | 800.20 | 793.60 | 239.10 | 1801.20 | 19683.10 | 681.20 | 820.00 | 777.00 | 301.50 | 812.00 | 865.00 | 917.00 | 780.00 | 402.00 |
| Pb | 33.30 | 7.20 | 1.00 | 320.90 | 79.60 | 45.60 | 4.50 | 194.30 | 1.50 | 1.30 | 1.30 | 1.20 | 1.20 | 13.80 | 64.10 | 139.30 | 2.50 | 54500.00 | 8.10 | 8.90 |
| Trace elements (%) | ||||||||||||||||||||
| V % | 0.11 | 0.06 | 0.07 | 0.02 | 0.03 | 0.13 | 0.06 | 0.03 | 0.04 | 0.04 | 0.04 | 0.06 | 0.05 | 0.04 | 0.04 | 0.04 | 0.02 | 0.15 | 0.01 | 0.01 |
| Co % | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.00 | 0.01 | 0.01 | 0.00 | 0.00 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| Ni % | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.12 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| Cu % | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.00 | 0.00 |
| (Co + Ni)% | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.00 | 0.00 | 0.01 | 0.12 | 0.01 | 0.01 | 0.00 | 0.00 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| (Co + Cu + Ni)% | 0.01 | 0.00 | 0.00 | 0.01 | 0.01 | 0.00 | 0.00 | 0.02 | 0.13 | 0.01 | 0.01 | 0.01 | 0.01 | 0.01 | 0.00 | 0.01 | 0.01 | 0.01 | 0.00 | 0.00 |
| (Co + Cu + Ni)%*10 | 0.06 | 0.03 | 0.04 | 0.05 | 0.10 | 0.04 | 0.04 | 0.15 | 1.26 | 0.08 | 0.08 | 0.09 | 0.07 | 0.09 | 0.04 | 0.05 | 0.06 | 0.09 | 0.01 | 0.01 |
| (Co + Cu + Ni)ppm/1000 | 0.06 | 0.03 | 0.04 | 0.05 | 0.10 | 0.04 | 0.04 | 0.15 | 1.26 | 0.08 | 0.08 | 0.09 | 0.07 | 0.09 | 0.04 | 0.05 | 0.06 | 0.09 | 0.01 | 0.01 |
| Zn % | 0.11 | 0.99 | 0.10 | 0.15 | 0.18 | 0.14 | 0.13 | 0.06 | 0.04 | 0.03 | 0.03 | 0.04 | 0.04 | 0.05 | 0.09 | 0.12 | 0.20 | 0.19 | 0.07 | 0.04 |
| Mo % | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| Ba % | 0.59 | 0.57 | 0.45 | 1.80 | 0.47 | 1.10 | 0.62 | 1.30 | 0.33 | 0.48 | 0.48 | 0.43 | 0.58 | 0.48 | 0.91 | 0.85 | 1.75 | 0.55 | 0.04 | 0.07 |
| As % | 0.09 | 0.09 | 0.08 | 0.08 | 0.08 | 0.08 | 0.08 | 0.08 | 0.02 | 0.18 | 1.97 | 0.07 | 0.08 | 0.08 | 0.03 | 0.08 | 0.09 | 0.09 | 0.08 | 0.04 |
| Pb % | 0.00 | 0.00 | 0.00 | 0.03 | 0.01 | 0.00 | 0.00 | 0.02 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.01 | 0.00 | 5.45 | 0.00 | 0.00 |
| (As + Cu + Mo + Pb + V + Zn) % | 0.31 | 1.14 | 0.25 | 0.27 | 0.30 | 0.35 | 0.27 | 0.19 | 0.11 | 0.25 | 2.04 | 0.17 | 0.18 | 0.16 | 0.16 | 0.25 | 0.31 | 5.88 | 0.16 | 0.08 |