Table 3.
Adsorption model | Parameter | Adsorbent | |||
---|---|---|---|---|---|
SBA-15-AP | SBA-15-MAP | SBA-15-DMAP | SBA-15-AEAP | ||
Langmuir | QL(max) (mg/g) | 169.5 | 151.5 | 61.0 | 178.6 |
KL (dm3/mg) | 2.745 × 10−3 | 2.794 × 10−3 | 3.072 × 10−4 | 2.384 × 10−3 | |
r 2 | 0.9992 | 0.9970 | 0.9903 | 0.9993 | |
Freundlich | KF (mg1−1/ndm3/n/g) | 2.973 | 2.413 | 2.923 × 10−2 | 2.868 |
nF | 1.948 | 1.879 | 1.126 | 1.938 | |
r 2 | 0.9440 | 0.9680 | 0.9941 | 0.9422 | |
Redlich−Peterson | KRP (dm3/g) | 0.488 | 0.479 | − | 0.441 |
aRP (dm3β/mgβ) | 6.698 × 10−3 | 1.581 × 10−2 | − | 4.144 × 10−3 | |
β | 0.883 | 0.778 | − | 0.931 | |
r 2 | 0.9993 | 0.9978 | − | 0.9949 | |
Temkin | KT (dm3/mg) | 3.765 × 10−2 | 3.032 × 10−2 | 4.372 × 10−3 | 3.571 × 10−2 |
bT (J g/mol mg) | 72.74 | 72.42 | 157.1 | 72.93 | |
r 2 | 0.9839 | 0.9659 | 0.8247 | 0.9883 | |
Dubinin–Radushkevich | QDR(max) (mg/g) | 286.3 | 272.9 | 98.4 | 284.6 |
KDR (mol2/J2) | 8.110 × 10−9 | 8.369 × 10−9 | 1.616 × 10−8 | 8.209 × 10−9 | |
EDR (kJ/mol) | 7.85 | 7.73 | 5.56 | 7.80 | |
r 2 | 0.9901 | 0.9971 | 0.9703 | 0.9891 | |
Dubinin–Astakhov | QDA(max) (mg/g) | 210.4 | 237.9 | − | 203.0 |
KDA (molnDA/JnDA) | 5.462 × 10−12 | 6.442 × 10−10 | − | 2.030 × 10−12 | |
nDA | 2.733 | 2.257 | − | 2.834 | |
EDA (kJ/mol) | 9.34 | 8.35 | − | 9.45 | |
r 2 | 0.9988 | 0.9982 | − | 0.9996 |