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. 2019 Nov 7;12(22):3671. doi: 10.3390/ma12223671

Table 3.

Isotherm parameters calculated from linear regression for 18β-glycyrrhetinic acid adsorption onto mesoporous silica functionalized with various amine groups.

Adsorption model Parameter Adsorbent
SBA-15-AP SBA-15-MAP SBA-15-DMAP SBA-15-AEAP
Langmuir QL(max) (mg/g) 169.5 151.5 61.0 178.6
KL (dm3/mg) 2.745 × 10−3 2.794 × 10−3 3.072 × 10−4 2.384 × 10−3
r 2 0.9992 0.9970 0.9903 0.9993
Freundlich KF (mg1−1/ndm3/n/g) 2.973 2.413 2.923 × 10−2 2.868
nF 1.948 1.879 1.126 1.938
r 2 0.9440 0.9680 0.9941 0.9422
Redlich−Peterson KRP (dm3/g) 0.488 0.479 0.441
aRP (dm/mgβ) 6.698 × 10−3 1.581 × 10−2 4.144 × 10−3
β 0.883 0.778 0.931
r 2 0.9993 0.9978 0.9949
Temkin KT (dm3/mg) 3.765 × 10−2 3.032 × 10−2 4.372 × 10−3 3.571 × 10−2
bT (J g/mol mg) 72.74 72.42 157.1 72.93
r 2 0.9839 0.9659 0.8247 0.9883
Dubinin–Radushkevich QDR(max) (mg/g) 286.3 272.9 98.4 284.6
KDR (mol2/J2) 8.110 × 10−9 8.369 × 10−9 1.616 × 10−8 8.209 × 10−9
EDR (kJ/mol) 7.85 7.73 5.56 7.80
r 2 0.9901 0.9971 0.9703 0.9891
Dubinin–Astakhov QDA(max) (mg/g) 210.4 237.9 203.0
KDA (molnDA/JnDA) 5.462 × 10−12 6.442 × 10−10 2.030 × 10−12
nDA 2.733 2.257 2.834
EDA (kJ/mol) 9.34 8.35 9.45
r 2 0.9988 0.9982 0.9996