Table 2.

Characterization of compounds in Gout Party

No.	tR (min)	m/z Obsd	m/z Calcd	Fromula	Identification	Parention	MS/MS
1	5.19	461.1674	461.1659	C20H30O12	Decaffeoyl-verbascoside	[M–H]−	161.04;135.04
2	5.86	486.2701	486.2703	C24H39NO9	Mesaconine	[M+H]+	468.25;454.24
3	6.17	387.1321	387.1291	C17H24O10	Genipin	[M–H]−	225.07
4	6.64	454.2778	454.2805	C24H39NO7	Fuziline	[M+H]+	436.28;404.28
5	6.86	358.2365	358.2382	C22H31NO3	Songorine	[M+H]+	340.23
6	7.33	500.2831	500.286	C25H41NO9	Aconine	[M+H]+	482.27;468.25
7	8.03	523.1666	523.1663	C21H32O15	Miltide	[M–H]−	463.14;343.10
8	8.58	470.2725	470.2754	C24H39NO8	Hypaconine	[M+H]+	438.24;406.22
9	8.76	454.2769	454.2805	C24H39NO7	Delectinine	[M+H]+	436.26;404.24
10	9.26	438.2823	438.2856	C24H39NO6	Neoline	[M+H]+	420.27;388.24
11	9.64	468.2935	468.2961	C25H41NO7	Browniine	[M+H]+	450.28;436.26
12	9.94	468.2935	468.2961	C25H41NO7	Lycoctonine	[M+H]+	362.29; 393.30
13	10.59	422.2890	422.2906	C24H39NO5	Talatizamine	[M+H]+	390.26;372.25
14	12.07	452.3019	452.3012	C25H41NO6	Chasmanine	[M+H]+	420.27;388.24
15	14.26	606.2914	606.2914	C31H43NO11	10-OH-Benzoylmesaco-nine	[M+H]+	588.27;574.26;556.25
16	15.99	623.1956	623.1976	C29H36O15	Acteoside	[M–H]−	461.16 161.02
17	17.44	576.2809	576.2809	C30H41NO10	Unknown	[M+H]+	558.27;544.25;526.24
18	19.01	544.2915	544.2910	C30H41NO8	Gadenine	[M+H]+	512.26;494.25;484.23
19	21.12	604.3154	604.3122	C32H45NO10	Benzoylaconitine	[M+H]+	588.31
20	22.26	572.2848	572.2860	C31H41NO9	Pyromesaconitine	[M+H]+	554.27;540.25;522.24
21	22.35	574.3044	574.3016	C31H43NO9	BenzoylhypaconineS	[M+H]+	542.27;510.24
22	22.59	516.2947	516.2961	C29H41NO7	Unknown	[M+H]+	442.25;414.26
23	23.31	616.3135	616.3122	C33H45NO10	Pyrojesaconitine	[M+H]+	598.30;584.28;566.27
24	23.78	558.3096	558.3067	C31H43NO8	Deoxybenzoylhypaconitine	[M+H]+	526.27;508.27
25	23.88	648.3031	648.3020	C33H45NO12	Beiwutine	[M+H]+	588.29
26	24.95	556.2905	556.2910	C31H41NO8	Pyrohypaconitine	[M+H]+	524.26;492.23
27	25.25	586.3019	586.3016	C32H43NO9	Pyroaconitine	[M+H]+	568.29;554.27;472.21
28	25.64	632.3107	632.3071	C33H45NO11	16-O-demethylaconitine	[M+H]+	572.28;540.25;508.22
29	25.64	632.3107	632.3071	C33H45NO11	Mesaconitine	[M+H]+	572.30;540.30
30	27.00	570.3082	570.3067	C32H43NO8	Pyrodeoxyaconitine	[M+H]+	538.27;506.25;478.22
31	27.11	616.3145	616.3122	C33H45NO10	HypaconitineS	[M+H]+	584.28;556.28;524.26
32	27.66	628.3131	628.3122	C34H45NO10	Anhydroaconitine	[M+H]+	568.28;536.26;508.26
33	28.33	700.2738	700.2758	C39H41NO11	Trifoliolasine E	[M+H]+	640.25;578.23
34	28.55	630.3281	630.3278	C34H47NO10	Deoxyaconitine	[M+H]+	598.30;570.30;538.27
35	28.74	505.3532	505.3529	C30H48O6	16-Oxo-alisol A	[M+H]+	505.33;487.34
36	29.32	529.3539	529.3529	C32H48O6	Alisol C-23-acetate	[M+H]+	551.33;511.34
37	30.92	455.3502	455.3525	C30H46O3	Alisol I	[M+H]+	477.33;543.33
38	31.67	487.3411	487.3423	C30H46O5	Alisol C	[M+H]+	509.33;469.32
39	31.71	489.3563	489.3580	C30H48O5	Alisol F	[M+H]+	511.33;471.34
40	32.51	471.3463	471.3474	C30H46O4	Alisol H	[M+H]+	493.32;453.33
41	33.98	515.3711	515.3736	C32H50O5	Alisol B-23-acetate	[M+H]+	537.35;497.35