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. Author manuscript; available in PMC: 2020 Apr 5.
Published in final edited form as: ACS Catal. 2019 Mar 13;9(4):3260–3265. doi: 10.1021/acscatal.9b00181

Table 2.

Enantioselective Alkene Carboboration Scopea

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a

Reaction conditions: 1a–k (0.1 mmol), 2a–k (3 equiv), 3a (4 equiv), Pd(OAc)2 (10 mol%), L34 (20 mol%), BQ (20 mol%), NaF (2 equiv), HFIP/THF/DMF (2:2:1, 0.2 mL), 45 °C, O2, 5 d. Percentages refer to isolated yields. Diastereomeric ratios (dr) are >20:1 in all cases. The enantioselectivity was determined by SFC analysis. bKF (2 equiv), HFIP/THF (1:1, 0.2 mL), 60 °C, 2 d.