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. Author manuscript; available in PMC: 2020 Aug 7.
Published in final edited form as: Chem Commun (Camb). 2019 Aug 7;55(64):9467–9470. doi: 10.1039/c9cc03863a

Table 3.

Reaction scope with respect to ArSSAra

graphic file with name nihms-1059928-t0033.jpg
Entry (ArS)2 Product Yield, %
1 (PhS)2 graphic file with name nihms-1059928-t0034.jpg 89
2 (4-MeC6H4S)2 graphic file with name nihms-1059928-t0035.jpg 88
3 (4-tBuC6H4S)2 graphic file with name nihms-1059928-t0036.jpg 95
4 (4-ClC6H4S)2 graphic file with name nihms-1059928-t0037.jpg 72
5 (4-MeOC6H4S)2 graphic file with name nihms-1059928-t0038.jpg 68
6 (3-MeOC6H4S)2 graphic file with name nihms-1059928-t0039.jpg 64
7 (2-MeOC6H4S)2 graphic file with name nihms-1059928-t0040.jpg 62
8 graphic file with name nihms-1059928-t0041.jpg graphic file with name nihms-1059928-t0042.jpg 58
a

Reaction conditions: aryne precursor (0.25 mmol), ArSSAr (0.3 mmol), LDAM (0.5 mmol), Et2O/THF (19/1), 47 h, 0 °C. Yields are isolated yields. Please see the ESI for details.