Table 1.
metal complex | τi (ns) | αi | fi | (ns) | χR2 |
---|---|---|---|---|---|
Re–Cl in DCMa(air) | 159 | 1.000 | 1.00 | 159 | 2.64b |
Re–Cl in DCM (argon) | 436 | 1.000 | 1.00 | 436 | 4.74 |
Re–Cl–HSA (air) | 2102 | 0.026 | 0.418 | ||
473 | 0.128 | 0.468 | |||
17.4 | 0.847 | 0.114 | 1101 | 4.73 |
DCM, dichloromethane.
For calculation of χR2 the uncertainties in the phase and modulation was assumed to be 0.2 and 0.005, respectively.