Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
a) Definition of the methyl anion affinities (ΔG MA) of Michael acceptors. b) Correlation between experimentally determined electrophilicities E and methyl anion affinities ΔG MA in DMSO [calculated at the SMD(DMSO)/B3LYP/6‐311++G(3df,2pd)//B3LYP/6‐31G(d,p) level of theory, see Supporting Information for details] supplemented by data for the fluorescent probes M74–M82 (not included when calculating the correlation line).
