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. 2019 Oct 1;25(64):14555–14571. doi: 10.1002/chem.201903095

Scheme 5.

Scheme 5

Plausible mechanistic pathway of free‐radical addition of thiols to 2‐acetoxy pentopyranosyl glycals, shown on the example of d‐arabinose‐derived glycal 6. The productive routes resulting exclusively in 1,2‐cis thioglycosides are highlighted in green.