Table 3.

Hydrothiolation reactions of d‐ and l‐hexoglycals.

Entry	Alkene +thiol	Product	Temp.	Yield [%][a]	Ratio A:B
1	8+20 (1.2 equiv)		rt	80	1.3:1[b]
2			−80 °C	76	8.5:1
3			−120 °C	75	6:1
4	9+20 (1.2 equiv)		0 °C	67	2.3:1
5			−40 °C	95	1.5:1
6			−80 °C	95	1:1.2
7			−120 °C	95	1:1.2
8	10+20 (1.2 equiv)		rt	38	1:0[b]
9			−80 °C	92	1:0
10	11+20 (1.2–2.0 equiv)		rt	66	2.5:1[c]
11			−80 °C	81	5.5:1[d]

[a] Combined isolated yield; [b] data are taken from Ref. 23, 6 equiv, of thiol was used; [c] 2.0 equiv of thiol was used. [d] 1.2 equiv of thiol was used.