Table 1.

Fluorescence decay of [Os(phen)₂(aphen)](PF₆)₂

Solvent	τi (ns)	Δτia	αia	Δαia	fic	$\overline{\tau }(\text{ns})$d	${\chi }_R^2$
Acetonitrile	56.4	(0.4)a	1.0e		1.00	56.4	2.3b
Glycerol	138	(2.0)	1.0		1.00	138.0	16.4
	18.5	(3.0)	0.125	(0.008)	0.018
	145.4	(1.3)	0.875	(0.008)	0.982	143.0	1.8
Water (air)	61.8	(0.7)	1.00		1.00	61.8	5.71
	7.4	(−2.3, +2.8)	0.068	(−0.009, +0.02)	0.008
	63.5	(−0.7, +0.8)	0.932	(−0.02, +0.009)	0.992	63.0	2.7
	6.8	(−1.8, +2.4)	0.064	(−0.007, +0.011)	0.007
	62.9	(0.6)	0.936	(−0.01, +0.005)	0.981
	3300.0	(−2000.0, +30000.0)	0.00022	(−0.0002, +0.0005)	0.012	102.0	2.3
Water (Ar)	65.0	(5.0)	1.00		1.00	65.5	241.0
	61.0	(3.0)	0.998	(−0.004, +0.02)	0.852
	5300.0	(−3500.0, +62000)	0.0020	(−0.0002, +0.0004)	0.148	838.0	72.1
	5.1	(0.9)	0.32	(−0.01, +0.02)	0.029
	69.7	(0.9)	0.68	(−0.02, +0.1)	0.852
	11 000.0	(−3000.0,+ 7000.0)	0.0006	(−0.0002, + 0.003)	0.119	1360.0	3.1
	2.7	(−0.8, +0.6)	0.36	(−0.03, +0.05)	0.019
	58.0	(−6.0, +3.0)	0.52	(−0.1, +0.06)	0.593
	112.0	(20.0)	0.12	(−0.05, +0.08)	0.264
	21 000.0	(−6000.,+ 11000.0)	0.0003	(0.0001)	0.124	2660.0	1.4
BSA	111.0	(5.0)	1.00		1.00	111.0	96.5
	26.0	(2.0)	0.38	(0.02)	0.100
	143.0	(−3.0, +4.0)	0.62	(0.02)	0.900	131.0	5.3
	19.	(2.0)	0.29	(0.02)	0.056
	111.0	(−8.0, +7.0)	0.63	(−0.05, +0.03)	0.715
	280.0	(−40.0, +60.0)	0.08	(−0.04, +0.06)	0.229	145.0	1.8

^aStandard deviations calculated by the Support plane or Bootstrap methods [34].

^bFor experimental uncertainties δp = 0.3° and δm = 0.08.

^cFractional fluorescence intensity.

^dMean lifetime, $\overline{\tau }=\Sigma f_i{\tau }_i$.

^eRoom temperature.