Table 2.
Anisotropy decay of [Os(phen)2(aphen)](PF6)2 attached to BSA
| ϕi(ns)a,b | Δϕc | r0i | Δri | gi | Δgi | |
|---|---|---|---|---|---|---|
| 38.7 | (−1.1, +0.9)c | 0.07 | (−0.001, +0.001) | 1.0 | 2.11d | |
| 40.4 | (−0.3, +1.3) | 0.12 | (−0.04, +0.02) | 0.58 | (−0.11, +0.25) | |
| 0.23 | (−0.09, +0.73) | 0.42 | (−0.25, +0.11) | 1.84 |
[Os(phen)2(aphen)](PF6)2 in Tris 50 mM tris buffer (pH 9.0), room temperature.
Values calculated for triple exponential decay from Table 1.
Standard deviations calculated by the Monte Carlo method.
For experimental uncertainties δΔ = 0.3° and δΛ = 0.008.