TABLE 3.

Photophysical Parameters for the Fluorophores in Fig. 15

Fluorophore	Q	τ (ns)	knr (ns−1)	Γ (ns−1)	IS/IQ (obs)	IS/IQ (calc)b	IS/IQ (calc)c	IS/IQ (calc)d
RhB (1)a	0.95	3.04	0.02	0.31	1.1	1.09	1.01	1.47
RhB (2)	0.48	1.58	0.33	0.30	1.24	1.20	1.11	1.89
Rose bengal (3)	0.26	0.97	0.76	0.27	1.7	1.37	1.29	2.51
Rose bengal (4)	0.18	0.86	0.95	0.21	1.9	1.54	1.46	3.03
Erythrosin B (5)	0.035	0.08	12.1	0.44	2.95	3.53	3.49	6.40
[Ru(bpy)3]2+ (6)	0.023	350	0.003	5.7 × 10−5	4.7	4.62	4.59	7.25
Rose bengal (7)	0.02	0.09	10.9	0.22	4.9	5.06	5.04	7.51
Basic Fuscin (8)	0.018	0.01	98	2	5.1	5.41	5.40	7.69
[Ru(bpy)2(dppz)]2+ (9)	0.009	—	—	—	8.8	8.27	8.28	8.67
[Ru(bpy)2(dppz)]2+ (10)	≤0.001	—	—	—	18.0	18.1	18.1	9.82

^aNumbers correspond to those in Fig. 15.

^bCalculated using Eq. [A5] with G_F = 203, G_A = 17, d_m = 31 Å, and d_q = 40 Å fixed.

^cCalculated using G_F = 199, G_A = 1.0 fixed, d_m = 31 Å, and d_q = 40 Å fixed.

^dCalculated using G_F = 20 fixed, G_A = 97, d_m = 23 Å, and d_q = 40 Å.