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Close to octahedral symmetry of the [CrN6] cores and the different orientations of the pyridine ligands in a) [Cr(tpe)2]3+ and b) [Cr(ddpd)2]3+ complexes. The bridging atoms and hydrogen atoms of the ligands are omitted and the N‐Cr‐N (in red) and C‐N‐N‐C angles (in blue, green and orange) given in deg.
