Table 1.

Luminescence data of pertinent chromium(III) complexes. All data refer to deoxygenated solutions.

complex (solvent)	τ/ μs	Φ/ %	Ref.
[Cr(phen)3]3+ (CH3CN)	224	0.15	7, 15
[Cr(tpy)2]3+ (CH3CN)	0.14	<0.00089	7, 14
[Cr(ddpd)2]3+ (H2O)	898	11.0	3
[Cr(ddpd)2]3+ (D2O)	1164	14.0	3
[Cr([Dn]‐ddpd)2]3+ (CD3CN)	2300	30.0	20
[Cr(TAP[9]aneN3)]3+ (H2O)	265	–	16, 17
[Cr(TAP[9]aneN3)]3+ (D2O)	850	–	16, 17
[Cr(fac‐Me5‐D 3h‐tricosaneN6)]3+ (H2O)	235	–	18
[Cr(fac‐Me5‐D 3h‐tricosaneN6)]3+ (D2O)	1500	–	18
[Cr(5‐C≡CH‐bpy)(phen)2]3+ (CH3CN)	259	–	15
[Cr(ddpd)(tpy)]3+ (CH3CN)	1000	0.06	26