. Author manuscript; available in PMC: 2019 Dec 17.

Published in final edited form as: Metallomics. 2011 Jan 24;3(2):140–151. doi: 10.1039/c0mt00061b

Table 4.

Alteration of rates of true electron transfer rates by site-directed mutagenesis

Electron transfer reaction	Reaction rate at 30° C (s⁻¹)	ΔG° (kJ/mol)	λ (eV)	H_AB (cm⁻¹)	Reference
MADH to amicyanin	9.8	−3.2	2.3 ± 1	12 ± 7	93
MADH to M98Q amicyanin	0.2	−3.3	2.7 ± 1	12 ± 4	28
MADH to F97E amicyanin	0.2	−3.2	2.3 ± 1	3 ± 1	83
MADH to P94F amicyanin	53	−21.7	2.3 ± 1	5 ± 1	94

Amicyanin to cytochrome c-551i	87	+3.2	1.2 ± 1	0.3 ± 0.1	14
P94F amicyanin to cytochrome c-551i	0.6	+21.7	1.3 ± 1	0.3 ± 0.1	94

The reactions rates which were altered and the parameters which were altered that caused the change in rate are highlighted in red.