. Author manuscript; available in PMC: 2019 Dec 17.

Published in final edited form as: Metallomics. 2011 Jan 24;3(2):140–151. doi: 10.1039/c0mt00061b

Table 5.

Alteration of kinetic mechanism of electron transfer by site-directed mutagenesis

Electron transfer reaction	Reaction rate at 30° C (s⁻¹)	λ (eV)	H_AB (cm⁻¹)	Kinetic mechanism	Reference
MADH to amicyanin	9.8	2.3 ± 1	12 ± 7	True	93
MADH to M51A amicyanin	1.3	3.1 ± 1	142 ± 20	Gated	87

Amicyanin to cytochrome c-551i	87	1.2 ± 1	0.3 ± 0.1	True	14
P94A amicyanin to cytochrome c-551i	0.4	2.3 ± 1	8.3 ± 5.5	Coupled	86

The reactions rates and the parameters which were altered by the change in kinetic mechanism are highlighted in red.