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. Author manuscript; available in PMC: 2020 Dec 19.
Published in final edited form as: Angew Chem Int Ed Engl. 2019 Nov 7;58(52):18803–18807. doi: 10.1002/anie.201908939

Table 1.

Selected optimization experiments in the enantioselective π-allyliridium-C,O-benzoate catalyzed allylation of acetylenic ketone 1a.a

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a

Yields are of material isolated by silica gel chromatography. Enantioselectivities were determined by chiral stationary phase HPLC analysis. See Supporting Information for further experimental details.

b

3-NO2-4-CN-BzOH (10 mol%).