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Enantioselective π-allyliridium-C,O-benzoate catalyzed allylation of acetylenic ketones 1a-1n via 2-propanol-mediated reductive coupling with allyl acetate 2a.a
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Yields are of material isolated by silica gel chromatography. Enantioselectivities were determined by chiral stationary phase HPLC analysis. See Supporting Information for further experimental details.
