Table 2.
Semi-quantitative comparison of phenolic and aliphatic hydroxyl groups after demethylation based on 1H-NMR analysis of acetylated lignins.
Proton Arrangement |
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---|---|---|---|---|---|---|---|
Chemical Shift (ppm) | 8.38 | 8.10 | 6.95 | 3.82 | 2.27 | 2.03 | |
Acetylated AL | Molar Amount of Functional Groups in 1 g Lignin (mmol/g) |
7.02 | 6.38 | 1.54 | 0.52 | 0.37 | |
Acetylated HI-DL | 7.02 | 5.34 | 1.10 | 0.67 | 0.47 | ||
Acetylated HBr-DL | 7.02 | 6.11 | 1.18 | 0.64 | 0.47 |