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. 2019 Nov 30;8(1):A0077. doi: 10.5702/massspectrometry.A0077

Table 2. Surface tension and vaporization enthalpy for the solvents used for ESI MS.

Solvent Surface tension (mN/m)*1 Vaporization enthalpy (kJ/mol) *2
Water (H2O) 72.0 44.0
Methanol (CH3OH) 22.6 38.3
Acetonitrile (CH3CN) 30.0 33.8

*1 F. Charbonnier, C. Rolando, F. Saru, P. Hapiot, J. Pinson. Short time-scale observation of an electrospray current. Rapid Commun. Mass Spectrom. 7: 707–710, 1993. *2 J. S. Chickos, W. E. Acree, Jr. Enthalpies of vaporization of organic and organometallic compounds, 1880–2002. J. Phys. Chem. Ref. Data 32: 519, 2003.