. 2019 Nov 6;7(11):532. doi: 10.3390/microorganisms7110532

Table 4.

Concentrations of other positively identified mycotoxins and fungal metabolites in barley samples.

Toxin (µg kg⁻¹)	Lukas (Dual)			Maxim (Dual)			Vanessa (Brewing)
Toxin (µg kg⁻¹)	2016	2017	2018	2016	2017	2018	2016	2017	2018
15-Acetyldeoxynivalenol	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD
15-Hydroxyculmorin	5.69^b	17.6^a	1.70^c	5.27^a	5.14^b	3.99^c	4.19^b	8.60^a	1.85^c
15-Hydroxyculmoron	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	33.44^a	<LOD
3-Acetyldeoxynivalenol	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD
5-Hydroxyculmorin	<LOD	<LOD	<LOD	59.9^a	<LOD	<LOD	<LOD	<LOD	<LOD
Alternariol	1.50^b	<LOD	8.61^a	<LOD	<LOD	8.52^a	<LOD	<LOD	4.74^a
Alternariolmethylether	<LOD	<LOD	3.90^a	<LOD	<LOD	2.51^a	<LOD	<LOD	0.75^a
Alternariolmethylether-glucoside	11.4^c	12.5^b	24.1^a	16.1^b	23.8^a	15.0^c	12.2^b	22.8^a	7.15^c
Brevianamid	9.23^a	5.58^b	4.46^c	23.2^a	17.4^b	6.99^c	9.05^a	7.46^b	3.40^c
Citreorosein	2.33^b	<LOD	3.54^a	4.84^b	<LOD	7.39^a	9.76^b	13.3^a	6.60^c
Culmorin	18.6^b	36.2^a	0.15^c	<LOD	23.5^a	4.05^b	15.8^b	16.7^a	5.04^c
Cyclo(L-Pro-L-Tyr)	23.0^a	8.08^b	3.79^c	26.6^a	17.6^b	5.64^c	24.1^a	14.7^b	4.36^c
Cyclo(L-Pro-L-Val)	19.1^a	9.32^b	3.03^c	30.1^a	21.0^b	4.15^c	19.8^a	15.2^b	1.79^c
Deoxynivalenol	75.5^b	75.8^a	68.5^c	67.4^c	107.2^a	75.1^b	51.0^a	40.9^c	60.2^b
DON-3-glucoside	2.82^b	10.6^a	<LOD	1.64^b	3.35a	<LOD	1.86^b	3.59^a	<LOD
Emodin	1.94^a	0.08	1.51^b	5.33^a	0.19	5.14^b	9.06^a	4.23^c	5.86^b
Enniatin A	<LOD	<LOD	<LOD	0.03^a	<LOD	<LOD	<LOD	<LOD	<LOD
Enniatin A1	0.22^a	<LOD	<LOD	0.16^a	<LOD	<LOD	<LOD	<LOD	<LOD
Enniatin B	1.48^a	0.02^c	0.04^b	0.77^a	<LOD	0.08^b	0.08^a	<LOD	<LOD
Enniatin B1	0.87^a	0.11^b	<LOD	0.39^a	<LOD	<LOD	0.06^a	<LOD	<LOD
Enniatin B2	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD
Fumonisin B1	4.95^c	5.45^a	5.22^b	8.15^a	5.92^b	5.56^c	6.64^b	7.34^a	5.43^c
HT-2 toxin	<LOD	2.61^a	<LOD	<LOD	<LOD	<LOD	<LOD	<LOD	4.57^a
Lotaustralin	10.4^a	8.65^c	8.95^b	10.4^b	11.2^a	9.60^c	9.67^a	8.58^c	9.08^b
Moniliformin	1.25^b	1.79^a	<LOD	<LOQ	2.69^a	<LOD	0.17	3.14^a	1.28^b
Monocerin	3.77^a	<LOD	<LOD	1.33^a	0.20^b	<LOD	<LOD	<LOD	<LOD
Rugulusovin	2.36^a	0.70	0.91^b	2.63^a	1.94^b	1.50^c	1.48^a	0.60^c	0.77^b
T-2 toxin	1.26^b	1.65^a	<LOD	<LOD	0.44^b	0.50^a	1.79^b	0.05^c	13.1^a
Tentoxin	0.31^b	<LOD	0.33^a	<LOD	<LOD	0.21a	<LOD	0.42^a	<LOD
Tryptophol	61.6^a	37.1^c	38.3^b	64.3^a	41.6^b	39.0^c	53.6^a	40.7^c	41.2^b

Values are means of triplicate. Values in the same row (2016–2018 for each variety) with different letters a–c are significantly different (p < 0.05). LOD and LOQ values are shown in Table S1, Supplementary Materials.