(a) Schematic
for synthesis process of carbon dots (CDs). Initially,
the solution is clear. Gradually, with the increase in reaction temperature
and time, nucleation followed by growth (steps 1, 2) takes place with
a change in color of the solution from pale yellow to brown. Surface
functionalization will take place for SFCDs in step 3. (b) The corresponding
meaning of steps 1, 2, and 3 in the reaction mechanism is explained.
Carbon dots are formed by pyrolysis and then carbonization of citric
acid. ODE acts as a high-boiling-point solvent. For SFCDs, HDA acts
as a surface-functionalizing agent. (c) The synthesized bare CDs under
UV light show white-light emission. SFCDs under UV light show blue
(452 nm) to green (541 nm) color emissions at different HDA/citric
acid molar concentrations. Blue light for sample with molar concentration
ratio HDA/citric acid = 0.3, and green color for samples with molar
concentration ratios HDA/citric acid = 0.6, 1.0, and 1.3 (from left
to right).