Table 2.
Parameters of nonlinear kinetic models for the adsorption of Pb2+ ions onto the pristine and functionalized ECNFs at 298 K.
ECNFs | o-ECNFs | melam-ECNFs | PmPDA-ECNFs | |
---|---|---|---|---|
PFO | ||||
qe,exp | 81.52 | 244.28 | 412.20 | 309.11 |
qe, cal | 79.57 | 226.28 | 378.35 | 298.19 |
k1 | 0.0217 | 0.1195 | 0.2065 | 0.1815 |
R2 | 0.9822 | 0.9705 | 0.9550 | 0.9865 |
χ2 | 4.18 | 5.85 | 14.36 | 3.31 |
PSO | ||||
qt, cal | 88.28 | 235.55 | 388.49 | 305.21 |
K2 (×10−4) | 3.55 | 8.83 | 10.90 | 0.0014 |
R2 | 0.9943 | 0.9941 | 0.9731 | 0.9971 |
χ2 | 0.5855 | 1.21 | 8.77 | 0.7436 |
Elovich | ||||
α | 3.66 | 40372.04 | 5.66*E6 | 2.55*E8 |
β | 0.0075 | 0.05727 | 0.0462 | 0.0735 |
R2 | 0.9583 | 0.99165 | 0.9954 | 0.9963 |
χ2 | 4.74 | 1.79000 | 1.54 | 0.9294 |
Intraparticle diffusion | ||||
Kid(1) | 6.13 | 11.33 | 4.55 | 6.28 |
I | 5.85 | 130.18 | 316.26 | 235.27 |
R2 | 0.9711 | 0.9921 | 0.9671 | 0.9633 |
Kid(2) | 0.2368 | 1.31 | 0.8774 | 0.4887 |
I | 75.74 | 209.46 | 388.94 | 295.94 |
R2 | 0.4976 | 0.9734 | 0.7980 | 0.9585 |