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. 2019 Dec 2;116(51):25478–25483. doi: 10.1073/pnas.1909165116

Fig. 3.

Fig. 3.

Schematic model for the outwash of oxygenated basal meltwater to anoxic glaciomarine environments (not to scale). IFs deposited in ice-contact settings (within ∼2 km of the grounding line) are characterized by negative δ56Fe values and may feature negative Ce anomalies and Mn-oxide enrichment, indicative of oxidizing conditions. Ice-proximal IFs (∼2 to 10 km from the grounding line) display predominantly positive δ56Fe values and negligible to slight positive Ce anomalies. Ice-distal IFs (greater than ∼10 km from the grounding line) feature slight positive Ce anomalies and highly positive δ56Fe values, with negligible Mn oxides. These geochemical trends are indicative of oxygenated glaciomarine environments which could have supported aerobic eukaryotes despite widespread anoxia during extreme glaciation. Microaerophilic Fe-oxidizing bacteria may have proliferated where O2-bearing meltwater mixed with ferruginous seawater, potentially supporting heterotrophic food webs.