Official websites use .gov
A
.gov website belongs to an official
government organization in the United States.
Secure .gov websites use HTTPS
A lock (
) or https:// means you've safely
connected to the .gov website. Share sensitive
information only on official, secure websites.
Computed and experimental correlation between the logarithm of the PCET rate constant and the scaled free energy for four different para-substituents with the oxidant FeCp2+ for λ = 30 kcal/mol. Note that the calculations used the experimentally determined driving force for the H substituent as a reference and the experimentally determined rate constant for the CF3 substituent as a reference to clearly illustrate the slopes.
