Table 1.
Compound | [CN−] (µM) | τ1 (ns) | α1 | τ2 (ns) | α2 | χ2 | ||
---|---|---|---|---|---|---|---|---|
o-BMOQBAa | 0 | 26.71 | 1.0 | – | – | 26.71 | 26.71 | 1.33 |
5 | 26.33 | 1.0 | – | – | 26.33 | 26.33 | 1.13 | |
10 | 26.34 | 1.0 | – | – | 26.34 | 26.34 | 1.21 | |
15 | 26.19 | 1.0 | – | – | 26.19 | 26.19 | 1.30 | |
25 | 24.78 | 1.0 | – | – | 24.78 | 24.78 | 1.23 | |
35 | 0.324 | 0.0160 | 25.54 | 0.9840 | 25.53 | 25.14 | 1.35 | |
45 | 0.326 | 0.0184 | 25.10 | 0.9816 | 25.09 | 24.64 | 1.46 | |
50 | 0.455 | 0.0176 | 25.20 | 0.9824 | 25.19 | 24.76 | 1.41 | |
BMOQa | 0 | 27.30 | 1.0 | – | – | 27.30 | 27.30 | 1.08 |
5 | 27.04 | 1.0 | – | – | 27.04 | 27.04 | 1.10 | |
10 | 26.74 | 1.0 | – | – | 26.74 | 26.74 | 1.12 | |
15 | 26.53 | 1.0 | – | – | 26.53 | 26.53 | 1.06 | |
20 | 26.25 | 1.0 | – | – | 26.25 | 26.25 | 1.14 | |
30 | 25.86 | 1.0 | – | – | 25.86 | 25.86 | 1.17 | |
40 | 25.37 | 1.0 | – | – | 25.37 | 25.37 | 1.05 | |
50 | 25.00 | 1.0 | – | – | 25.00 | 25.00 | 1.16 |
λex = 372 nm, emission was collected with a 416 nm cut-off filter. BMOQ KSV ≈ 1840 M−1. The free columns indicate that the intensity decay was not described well by the addition of an extra decay time, τ2.