Table 2.
Compound | [CN−] (µM) | τ1 (ns) | α1 | τ2 (ns) | α2 | χ2 | ||
---|---|---|---|---|---|---|---|---|
o-BMQBAa | 0 | 2.18 | 0.4646 | 4.74 | 0.5354 | 4.01 | 3.55 | 1.00 |
5 | 2.14 | 0.4615 | 4.45 | 0.5385 | 3.78 | 3.38 | 1.12 | |
10 | 2.28 | 0.5704 | 4.75 | 0.4296 | 3.78 | 3.34 | 1.04 | |
15 | 1.86 | 0.3265 | 3.64 | 0.6735 | 3.29 | 3.06 | 0.97 | |
20 | 1.88 | 0.3476 | 3.69 | 0.6524 | 3.30 | 3.06 | 1.04 | |
30 | 1.44 | 0.1762 | 3.27 | 0.8238 | 3.11 | 2.95 | 1.21 | |
40 | 1.92 | 0.3511 | 3.59 | 0.6489 | 3.21 | 3.00 | 0.90 | |
50 | 1.87 | 0.3320 | 3.58 | 0.6680 | 3.22 | 3.01 | 1.07 | |
BMQa | 0 | 2.59 | 1.0 | – | – | 2.59 | 2.59 | 1.07 |
5 | 2.58 | 1.0 | – | – | 2.58 | 2.58 | 1.09 | |
10 | 2.59 | 1.0 | – | – | 2.59 | 2.59 | 1.07 | |
15 | 2.57 | 1.0 | – | – | 2.57 | 2.57 | 1.02 | |
20 | 2.57 | 1.0 | – | – | 2.57 | 2.57 | 1.12 | |
30 | 2.55 | 1.0 | – | – | 2.55 | 2.55 | 1.08 | |
40 | 2.55 | 1.0 | – | – | 2.55 | 2.55 | 1.14 | |
50 | 2.55 | 1.0 | – | – | 2.55 | 2.55 | 1.17 |
λex = 372 nm, emission was collected with a 416 nm cut-off filter. BMQ KSV ≈ 314 M−1. The free columns indicate that the intensity decay was not described well by the addition of an extra decay time, τ2.