TABLE 2:
DCS Intensity Decay Analysis in Absence and Presence of Light Quenching
| expected | found | ||||||
|---|---|---|---|---|---|---|---|
| solvent | τ (PS) | td (PS) | LQ | τ (ns) | td (ns) | q | XR2 |
| methanol | 463 | no | 463(1)a | 〈0〉b | 1.2 | ||
| 465(3) | 4(2) | 0.002(0.01) | 1.1 | ||||
| 463 | 36 | yes | 154 | 〈0〉 | 1189.7 | ||
| 〈463〉 | 〈36〉 | 0.72 | 1.0 | ||||
| 〈463〉 | 35(1) | 0.73(0.01) | 1.0 | ||||
| 456(3) | 33(2) | 0.73(0.01) | 0.9 | ||||
| 463 | 260 | yes | 314 | 〈0〉 | 255.0 | ||
| 〈463〉 | 〈260〉 | 0.54 | 1.2 | ||||
| 〈463〉 | 268(2) | 0.54(0.1) | 1.0 | ||||
| 461(3) | 269(2) | 0.54(0.1) | 0.9 | ||||
| ethylene glycol | 1130 | no | 1130(3) | 〈0〉 | 1.7 | ||
| 1180(6) | 284(5) | 0.05(0.01) | 1.3 | ||||
| 1130 | 570 | yes | 546 | 〈0〉 | 388.6 | ||
| 〈1130〉 | 〈570〉 | 0.66(0.01) | 1.9 | ||||
| 〈1130〉 | 573(2) | 0.66(0.01) | 1.9 | ||||
| 1060(4) | 570(2) | 0.63(0.01) | 1.4 | ||||
a
Standard deviations from the least-squares analysis.
b
The value of the parameter in brackets was kept constant during the analyses.