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. 2019 Dec 4;23(1):100755. doi: 10.1016/j.isci.2019.100755

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© 2019 The Author(s)

This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).

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Scheme 1 — Selective C(sp³)-H Functionalization via Hydrogen Atom Transfer of Alkoxyl Radicals

phth, Phthalimide. (A) Alkoxyl radicals enable C(sp^³)-H functionalization with intermolecular HAT, intramolecular 1,5-HAT or 1,2-HAT. (B) α-C(sp^³)-H allylation via 1,2-HAT of alkoxyl radical by photoredox catalysis with Hantzsch ester.