| Crystal data |
| Chemical formula |
[Co(C14H9Cl2N2O)2] |
[Cu(C14H9Cl2N2O)2] |
|
M
r
|
643.19 |
647.80 |
| Crystal system, space group |
Triclinic, P
|
Triclinic, P
|
| Temperature (K) |
296 |
296 |
|
a, b, c (Å) |
8.8137 (10), 10.4801 (12), 15.0785 (17) |
8.1300 (7), 8.5072 (11), 9.7386 (13) |
| α, β, γ (°) |
85.684 (7), 77.984 (7), 84.965 (7) |
83.240 (4), 87.646 (3), 81.533 (4) |
|
V (Å3) |
1354.7 (3) |
661.39 (14) |
|
Z
|
2 |
1 |
| Radiation type |
Mo Kα |
Mo Kα |
| μ (mm−1) |
1.06 |
1.27 |
| Crystal size (mm) |
0.35 × 0.30 × 0.30 |
0.35 × 0.35 × 0.30 |
| |
| Data collection |
| Diffractometer |
Bruker Kappa APEXII CCD |
Bruker Kappa APEXII CCD |
| Absorption correction |
Multi-scan (SADABS; Bruker, 2004 ▸) |
Multi-scan (SADABS; Bruker, 2004 ▸) |
|
T
min, T
max
|
0.631, 0.746 |
0.637, 0.714 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
45690, 6959, 4590 |
5554, 3090, 2708 |
|
R
int
|
0.102 |
0.021 |
| (sin θ/λ)max (Å−1) |
0.678 |
0.667 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.045, 0.112, 1.04 |
0.033, 0.093, 1.05 |
| No. of reflections |
6959 |
3090 |
| No. of parameters |
352 |
178 |
| H-atom treatment |
H-atom parameters constrained |
H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) |
0.45, −0.50 |
0.44, −0.46 |
