Table 2. Experimental details.
| Crystal data | |
| Chemical formula | [Ir(C9H7N2)2(C8H6N2)]PF6·CH2Cl2 |
| M r | 838.57 |
| Crystal system, space group | Monoclinic, P21/c |
| Temperature (K) | 293 |
| a, b, c (Å) | 12.1222 (3), 15.5510 (4), 17.1579 (5) |
| β (°) | 105.313 (1) |
| V (Å3) | 3119.64 (14) |
| Z | 4 |
| Radiation type | Mo Kα |
| μ (mm−1) | 4.57 |
| Crystal size (mm) | 0.20 × 0.18 × 0.15 |
| Data collection | |
| Diffractometer | APEXII CCD area detector |
| Absorption correction | Multi-scan (SADABS; Bruker, 2016 ▸) |
| T min, T max | 0.417, 0.504 |
| No. of measured, independent and observed [I > 2σ(I)] reflections | 36216, 6387, 5528 |
| R int | 0.032 |
| (sin θ/λ)max (Å−1) | 0.626 |
| Refinement | |
| R[F 2 > 2σ(F 2)], wR(F 2), S | 0.024, 0.062, 1.04 |
| No. of reflections | 6387 |
| No. of parameters | 388 |
| H-atom treatment | H-atom parameters constrained |
| Δρmax, Δρmin (e Å−3) | 1.29, −1.04 |