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. 2019 Dec 10;9(12):170. doi: 10.3390/membranes9120170
Abbreviations
AEM anion-exchange membrane
CEM cation-exchange membrane
KHT potassium hydrogen tartrate
ED electrodialysis
Subscript
1 counterion
A Co-ion
Symbols
ρH2O volumetric density of water, g cm–3
G0 Gibbs hydration energy, J mol
d thickness of the membranes, μm
h hydration number
Q ion-exchange capacity of the membrane, mmol g–1
V¯ partial molar volume of water, 18 cm3 mol–1
σ interfacial surface tension, 0.072 N m–1
θ contact angle, degree
nw number of water molecules per fixed group of AEM, molH2O mol–1 f.gr
V integral volume of sorbed water per gram of dry membrane, cm3 g–1dry
Vt total water content in the test sample, cm3 g–1dry
A binding energy of water, J mol–1
r pore effective radius, nm
P integral coefficient of diffusion permeability, cm2 s–1
P* differential coefficient of diffusion permeability, cm2 s–1
P¯ diffusion permeability of the membrane gel phase, cm2 s–1
D diffusion coefficient of the electrolyte, cm2 s–1
α structural parameter
ti¯ transport numbers of ions i in the gel phase
ti transport numbers of ions i in the electrolyte
f 1 volume fraction of gel phase in the membrane
f 2 volume fraction of intergel spaces in the membrane
c¯A concentration of co-ions of the gel phase, M
D¯A diffusion coefficient of co-ions in the gel phase, cm2 s–1
zi charge number of ion i
KD Donnan constant
Kji ion-exchange equilibrium constant for i and j counterions