| Abbreviations |
| AEM |
anion-exchange membrane |
| CEM |
cation-exchange membrane |
| KHT |
potassium hydrogen tartrate |
| ED |
electrodialysis |
| Subscript |
|
1
|
counterion |
|
A
|
Co-ion |
| Symbols |
|
|
volumetric density of water, g cm–3
|
|
|
Gibbs hydration energy, J mol |
|
d
|
thickness of the membranes, μm |
|
h
|
hydration number |
|
Q
|
ion-exchange capacity of the membrane, mmol g–1
|
|
|
partial molar volume of water, 18 cm3 mol–1
|
|
|
interfacial surface tension, 0.072 N m–1
|
| θ |
contact angle, degree |
|
nw
|
number of water molecules per fixed group of AEM, molH2O mol–1
f.gr
|
|
V
|
integral volume of sorbed water per gram of dry membrane, cm3 g–1dry
|
|
Vt
|
total water content in the test sample, cm3 g–1dry
|
|
A
|
binding energy of water, J mol–1
|
|
r
|
pore effective radius, nm |
|
P
|
integral coefficient of diffusion permeability, cm2 s–1
|
|
P*
|
differential coefficient of diffusion permeability, cm2 s–1
|
|
|
diffusion permeability of the membrane gel phase, cm2 s–1
|
|
D
|
diffusion coefficient of the electrolyte, cm2 s–1
|
| α |
structural parameter |
|
|
transport numbers of ions i in the gel phase |
|
|
transport numbers of ions i in the electrolyte |
|
f
1
|
volume fraction of gel phase in the membrane |
|
f
2
|
volume fraction of intergel spaces in the membrane |
|
|
concentration of co-ions of the gel phase, M |
|
|
diffusion coefficient of co-ions in the gel phase, cm2 s–1
|
|
zi
|
charge number of ion i
|
|
KD
|
Donnan constant |
|
|
ion-exchange equilibrium constant for i and j counterions |