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. 2019 Dec 13;7(12):697. doi: 10.3390/microorganisms7120697

Table 2.

MFCs for the removal of heavy metals from soil.

Metal MFC Fabrication Reduction Reaction Description Maximum RemovalEfficiency Maximum Power Generation References
Cu(II) Single-chamber MFC
Granular activated carbon
for anode and cathode
Cu 600 mg/kg, sodium acetate 6.00 g/L,
pH = 7.0, 56 d
N/A 65.77 mW/m2 [74]
Pb(II) and
Cd(II)
Two-chamber MFC,
Graphite granules for anode,
Carbon felt for cathode
i. Pb(II) 910 mg/kg, 108 d;
ii. Cd(II) 98 mg/kg, 143 d;
acetate 1.36 g/L, pH = 6.7
i. 44.1%
ii. 31.0%
i. 3.6 mW/cm2
ii. 7.5 mW/cm2
[75]
Cr(VI) Two-chamber MFC
Carbon felts for anode,
Carbon felts for cathode
Cr(VI) 255 mg/kg in red clay soil, pH = 4.80;
Cr(VI) 550 mg/kg in the fluvo-aquic soil, pH = 7.04;
sodium acetate 2.00 g/L,16 d
99.1%
(in fluvo-aquic soil with 100 Ω)
N/A [76]
Zn(II) andCd(II) Three-chamber MFC
Graphite mat for anode,
Graphite mesh/ Pt coated for cathode
Zn(II) 11.6 g/kg, Cd(II) 0.84 g/kg,
sodium acetate 2 g/L, 78 d, pH = 3.0
25% (Zn)
18% (Cd)
0.4A/m2 [77]
Cr(VI) Single-chamber plant MFC
Graphite granules for carbon,
Carbon felt for cathode
Cr(VI) 9.5mg/L and 19 mg/L
sodium acetate 1 mM,
Lolium perenne,
1/2 Hoagland’s solution, greenhouse
99% 55 mA/m2 [16]
Cr(VI) Single-chamber plant MFC
Carbon felts or graphite carbon felts for the anode and the cathode
Cr(IV) 500 mg/kg,
Pennisetum alopecuroides,
Phragmites communis
greenhouse, 96 d
99% 469.21 mV [78]